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What is an Isotope?

Barrels most likely filled with uranium are stamped with the universal warning sign for radioactivity.
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  • Originally Written By: Michael Anissimov
  • Revised By: Phil Riddel
  • Edited By: Niki Foster
  • Last Modified Date: 02 April 2014
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An isotope is a variant on an element that has a different atomic weight from other variants. Except for the commonest form of hydrogen — which has only a proton — every atomic nucleus in normal matter is made of both protons and neutrons. Isotopes of a given element have the same number of protons, but different numbers of neutrons. They have essentially the same chemical properties, but differ slightly in their physical characteristics, such as melting point and boiling point. Some isotopes are unstable and tend to decay into other elements, giving off subatomic particles or radiation; these are radioactive and are known as radioisotopes.

When scientists refer to a particular isotope of an element, the mass number, or the number of protons plus the number of neutrons, appears at the top left, next to the symbol for the element. For example, the form of hydrogen that has a proton and a neutron is written as 2H. Similarly, 235U and 238U are two different isotopes of uranium. These are also commonly written as uranium-235 and uranium-238.

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The Atomic Nucleus

Neutrons are electrically neutral, but protons have a positive electrical charge. Since like charges repel, a nucleus containing more than one proton needs something to prevent these particles from flying apart. That something is called the strong nuclear force, sometimes referred to as simply the strong force. It is much stronger than the electromagnetic force that is responsible for the repulsion between protons, but unlike this force, it has a very short range. The strong force binds protons and neutrons together in the nucleus, but the electromagnetic force wants to push the protons apart.

Stable and Unstable Nuclei

In the lighter elements, the strong force is able to hold the nucleus together as long as there are enough neutrons to dilute the electromagnetic force. Typically, in these elements, the numbers of protons and neutrons are about the same. In heavier elements, there has to be an excess of neutrons to provide stability. Beyond a certain point, however, there is no configuration that provides a stable nucleus. None of the elements heavier than lead have any stable isotopes.

Too many neutrons can also make an isotope unstable. For example, the commonest form of hydrogen has one proton and no neutrons, but there are two other forms, with one and two neutrons, called deuterium and tritium, respectively. Tritium is unstable because it has too many neutrons.

When an unstable, or radioactive, nucleus decays, it turns into a nucleus of another element. There are two mechanisms by which this can happen. Alpha decay happens when the strong force cannot hold all the protons in a nucleus together. Instead of just throwing out a proton, however, an alpha particle consisting of two protons and two neutrons is ejected. Protons and neutrons are tightly bound together and the alpha particle is a stable configuration.

Beta decay occurs when a nucleus has too many neutrons. One of the neutrons turns into a proton, which remains in the nucleus, and an electron, which is ejected. In tritium, for example, one of its two neutrons will, sooner or later, turn into a proton and an electron. This gives a nucleus with two protons and one neutron, which is a form of helium, known as 3He or helium-3. This isotope is stable, despite the excess of protons, because the nucleus is small enough for the strong force to hold it together.

Half-Lives

There is a fundamental uncertainty about the time it will take for an individual unstable nucleus to decay; however, for a given isotope, the rate of decay is predictable. It is possible to give a very precise value for the amount of time it will take for half of a sample of a particular isotope to decay into another element. This value is known as the half-life and can vary from a tiny fraction of a second to billions of years. The most common form of the element bismuth has a half-life a billion times as long as the estimated age of the universe. It was once thought to be the heaviest stable element, but was proved to be very slightly radioactive in 2003.

Properties

Besides the issue of radioactivity, different isotopes of an element show differing physical properties. Heavier forms, with more neutrons, typically have higher melting and boiling points, due to the fact that more energy is required to make their atoms and molecules move fast enough to bring about a change of state. For example, “heavy water,” a form of water in which normal hydrogen is replaced by the heavier deuterium, freezes at 38.9°F (3.82°C) and boils at 214.5°F (101.4°C), as opposed to 32°F (0°C) and 212°F (100°C), respectively, for ordinary water. Chemical reactions may proceed slightly more slowly for heavier isotopes for the same reason.

Uses

Probably the most famous isotope is 235U, because of its use in nuclear energy and weaponry. Its instability is such that it can undergo a nuclear chain reaction, releasing huge amounts of energy. “Enriched” uranium is uranium with a higher concentration of this isotope, while “depleted” uranium has a much lower concentration.

Radiometric dating uses the proportions of different isotopes to estimate the age of samples, such as biological materials or rocks. Radiocarbon dating, for example, uses the radioactive isotope 14C, or carbon-14, to date materials containing carbon of organic origin. The age and geological history of the Earth are known largely through comparing the proportions of various isotopes in rock samples.

In biology and medicine, small amounts of slightly radioactive isotopes can be used as atomic markers to trace the movement of various substances, such as drugs, through the body. More strongly radioactive isotopes may be used as a source of radiation to destroy tumors and cancerous growths. Helium-3, thought to exist in large quantities on the moon, is among the most promising long-term fuels for fusion power reactors. Using it effectively will require first mastering other forms of fusion, however.

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Discuss this Article

anon297948
Post 64

This helps a lot when a chemistry test is tomorrow and helps just in case the professor might give us a pop quiz.

anon146965
Post 50

To people who said this was simple: Well, I'm in 5th grade, and I'm working on a science project. This isn't exactly easy for me to understand, because I'm 10, but I figure it out. Eventually.

Thank you wiseGEEK! You are a lot easier to understand then Wikipedia sometimes. (I'm 10, duh. We don't understand everything!)

anon130725
Post 48

thanks guys, my teacher would be amazed.

anon94142
Post 39

thank you this was very helpful.

anon93467
Post 38

Where can you find a site for how they discovered isotopes?

anon75264
Post 27

hooray! thank you wisegeek. after reading other websites, I thought I'd never understand Isotopes.

anon72091
Post 26

Wow, thanks. i love you guys!

anon71345
Post 25

This is helpful. my teacher will be pleased.

anon68833
Post 23

thanks a lot!

anon68452
Post 22

i like science. it is very fun. thank you very much good friends at wisegeek.

anon68046
Post 21

what is the difference between natural and synthetic isotopes? I really need to know the answer to that, thanks anyway

anon65028
Post 19

this site is so helpful. i love you guys.

anon64175
Post 17

Thank you! Why can't all websites explain things in plain language! I finally get it!

anon51757
Post 12

Good use of website.

anon45586
Post 10

this is good information clearing mind with simple language.

anon45465
Post 9

thanks for the info.

anon45464
Post 8

yes frederick soddy received a nobel prize in 1921.

laluna
Post 3

Frederick Soddy received Nobel Prize in 1921, for his contributions and work with isotopes.

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